d and f Block ElementshardNUMERICAL

A specific divalent cation () in the transition series causes a sharp break in the linearly increasid and f Block Elements Chemistry Question

Question

A specific divalent cation ($M^{2+}$) in the $3d$ transition series causes a sharp break in the linearly increasing trend of the third ionization enthalpy due to its exchange-energy stabilized configuration. How many unpaired electrons does this specific $M^{2+}$ cation possess in its ground state?

Answer: 5

💡 Solution & Explanation

The element is Manganese ($Mn$). Its second ionization leaves the highly stable $Mn^{2+}$ ion with an exactly half-filled $3d^5$ configuration. Removing a third electron to form $Mn^{3+}$ requires breaking this stability, resulting in an unusually high third ionization enthalpy. The $3d^5$ configuration possesses exactly $5$ unpaired electrons.

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