d and f Block ElementshardMCQ MULTIPLE

Which of the following elements have a melting point significantly higher than that of Iron () withid and f Block Elements Chemistry Question

Question

Which of the following elements have a melting point significantly higher than that of Iron ($Fe$) within their respective transition series?

Answer: A,C

💡 Solution & Explanation

The melting point of transition metals roughly correlates with the number of unpaired $d$ -electrons available for bonding. Chromium ($Cr$) has $6$ unpaired electrons ($3d^5 4s^1$) and has the maximum melting point in the $3d$ series, higher than $Fe$. Tungsten ($W$) in the $5d$ series has exceptionally strong metallic bonding and the highest melting point of all metals. $Mn$ has a localized stable $d^5$ state causing a dip in its melting point (lower than $Fe$). $Zn$ ($d^{10}$) has the lowest.

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