Coordination CompoundshardMCQ SINGLE

According to Werner's theory, the primary and secondary valencies of Cobalt in the complex are respeCoordination Compounds Chemistry Question

Question

According to Werner's theory, the primary and secondary valencies of Cobalt in the complex $[Co(NH_3)_4Cl_2]Cl$ are respectively:

Answer: A

💡 Solution & Explanation

Primary valency equals the oxidation state of the central metal ion. Let the oxidation state of Co be $x$. $x + 4(0) + 2(-1) = +1 \Rightarrow x = +3$. Hence, primary valency is $3$. Secondary valency equals the coordination number, which is the number of ligand donor atoms directly attached to the metal. There are $4$ ammine ligands and $2$ chlorido ligands, making the secondary valency $4 + 2 = 6$.

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