Chemical BondinghardNUMERICAL

What is the total number of electrons present specifically in the antibonding molecular orbitals () Chemical Bonding Chemistry Question

Question

What is the total number of electrons present specifically in the antibonding molecular orbitals ($N_a$) of a single $O_2$ molecule in its ground state?

Answer: 6

💡 Solution & Explanation

An $O_2$ molecule contains 16 total electrons. The MOT filling order is $\sigma 1s^2, \sigma^* 1s^2, \sigma 2s^2, \sigma^* 2s^2, \sigma 2p_z^2, \pi 2p_x^2 = \pi 2p_y^2, \pi^* 2p_x^1 = \pi^* 2p_y^1$. The antibonding orbitals ($\sigma^* 1s$, $\sigma^* 2s$, $\pi^* 2p_x$, $\pi^* 2p_y$) contain $2 + 2 + 1 + 1 = 6$ electrons.

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