Atomic StructuremediumNUMERICAL

Let be the number of nodal planes in a orbital, and be the number of nodal surfaces (radial nodes) iAtomic Structure Chemistry Question

Question

Let $a$ be the number of nodal planes in a $d_{x^2-y^2}$ orbital, and $b$ be the number of nodal surfaces (radial nodes) in a $4s$ orbital. Calculate the product $(a \times b)$.

Answer: 6

💡 Solution & Explanation

The number of nodal planes (angular nodes) equals $l$. For a $d$ orbital ($l=2$), $a = 2$. Specifically, $d_{x^2-y^2}$ has two nodal planes at a $45^\circ$ angle to the $x$ and $y$ axes. The number of radial nodes is $(n-l-1)$. For a $4s$ orbital ($n=4, l=0$), $b = 4 - 0 - 1 = 3$. The product $(a \times b) = 2 \times 3 = 6$.

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