Aromatic HydrocarbonshardMCQ SINGLE

Arrange the following groups in decreasing order of their activating power towards electrophilic aroAromatic Hydrocarbons Chemistry Question

Question

Arrange the following groups in decreasing order of their activating power towards electrophilic aromatic substitution: $-NH_2$, $-OH$, $-NHCOCH_3$, $-CH_3$.

Answer: B

💡 Solution & Explanation

The activating power depends on the ability to donate electrons via resonance. Nitrogen is less electronegative than oxygen, making $-NH_2$ a stronger $+M$ donor than $-OH$. The $-NHCOCH_3$ group is moderately activating because its lone pair is cross-conjugated with the carbonyl group, reducing its availability to the aromatic ring. Alkyl groups like $-CH_3$ activate weakly only via hyperconjugation and $+I$ effects.

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