The relative reactivity of carbonyl compounds towards nucleophilic addition is governed by electroni — Aldehydes Ketones and Carboxylic Acids Chemistry Question
Question
The relative reactivity of carbonyl compounds towards nucleophilic addition is governed by electronic and steric factors. Which of the following statements are true?
Answer: A,B,D
💡 Solution & Explanation
Ketones have two alkyl groups causing steric crowding and +I effects (lowering reactivity). Formaldehyde has only hydrogens, making it the most reactive. Benzaldehyde is actually LESS reactive than aliphatic aldehydes because the -M/resonance effect of the carbonyl group pulls electron density from the ring, stabilizing the carbonyl carbon's positive charge.
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