When exactly of glycerol (propane-1,2,3-triol) is completely oxidized and cleaved by an excess of pe — Alcohols Phenols and Ethers Chemistry Question
Question
When exactly $1 \text{ mole}$ of glycerol (propane-1,2,3-triol) is completely oxidized and cleaved by an excess of periodic acid ($HIO_4$), how many moles of methanal (formaldehyde, $HCHO$) are yielded as final organic products?
Answer: 2
💡 Solution & Explanation
The oxidative cleavage of glycerol by $HIO_4$ breaks both $C-C$ bonds. The two terminal primary alcohol groups ($-CH_2OH$) are oxidized to two moles of methanal ($HCHO$). The central secondary alcohol group ($-CHOH-$) is doubly oxidized to one mole of methanoic acid (formic acid, $HCOOH$). Thus, 2 moles of methanal are produced.
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