Alcohols Phenols and EthershardNUMERICAL

When exactly of glycerol (propane-1,2,3-triol) is completely oxidized and cleaved by an excess of peAlcohols Phenols and Ethers Chemistry Question

Question

When exactly $1 \text{ mole}$ of glycerol (propane-1,2,3-triol) is completely oxidized and cleaved by an excess of periodic acid ($HIO_4$), how many moles of methanal (formaldehyde, $HCHO$) are yielded as final organic products?

Answer: 2

💡 Solution & Explanation

The oxidative cleavage of glycerol by $HIO_4$ breaks both $C-C$ bonds. The two terminal primary alcohol groups ($-CH_2OH$) are oxidized to two moles of methanal ($HCHO$). The central secondary alcohol group ($-CHOH-$) is doubly oxidized to one mole of methanoic acid (formic acid, $HCOOH$). Thus, 2 moles of methanal are produced.

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