Haloalkanes and HaloareneshardMCQ SINGLE

Hydrocarbon (A) reacts with bromine by substitution to form an alkyl bromide which by Wurtz reactionHaloalkanes and Haloarenes Chemistry Question

Question

Hydrocarbon (A) reacts with bromine by substitution to form an alkyl bromide which by Wurtz reaction is converted to a gaseous hydrocarbon containing less than four carbon atoms. A is:

Answer: D

💡 Solution & Explanation

The final product of the Wurtz reaction is a gaseous alkane with fewer than four carbon atoms, which must be ethane ($C_2H_6$). Ethane is symmetrically formed by the coupling of methyl bromide ($CH_3Br$). Therefore, the original starting hydrocarbon (A) must be methane ($CH_4$).

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