Thermodynamics and ThermochemistryhardMCQ MULTIPLE

According to strict IUPAC thermochemical conventions, which of the following elemental substances poThermodynamics and Thermochemistry Chemistry Question

Question

According to strict IUPAC thermochemical conventions, which of the following elemental substances possess a definitively non-zero standard molar enthalpy of formation ($\Delta_f H^\circ eq 0$) at $298 \text{ K}$ and $1 \text{ bar}$?

Answer: A,B,C,D

💡 Solution & Explanation

Standard states dictate $\Delta_f H^\circ = 0$ exclusively for pure elements residing in their most thermodynamically stable reference allotrope or phase. For Carbon, the stable reference is graphite (diamond is $ eq 0$). For Sulphur, it is rhombic (monoclinic is $ eq 0$). For Bromine, it is liquid $Br_2(l)$ (gaseous is $ eq 0$). For Phosphorus, highly reactive white phosphorus is the accepted reference (red is $ eq 0$).

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