Certain non-Newtonian colloidal gels, such as classic ferric hydroxide gels and modern commercial pa — Surface Chemistry Chemistry Question
Question
Certain non-Newtonian colloidal gels, such as classic ferric hydroxide gels and modern commercial paints, undergo a severe viscosity drop to essentially liquefy and form a fluid sol when mechanically agitated, but they spontaneously reset back into a semi-rigid gel when entirely allowed to stand. What is this completely reversible isothermal sol-gel transformation explicitly named?
💡 Solution & Explanation
Thixotropy is the unique, highly specific rheological property where a semi-rigid gel reversibly transforms into a highly fluid sol under the strict application of mechanical shear stress (such as shaking or stirring) and reversibly sets entirely back into a solid-like gel state when the external shear is fully removed.