The topical application of an aqueous solution of ferric chloride () or alum directly to a bleeding — Surface Chemistry Chemistry Question
Question
The topical application of an aqueous solution of ferric chloride ($FeCl_3$) or alum directly to a bleeding wound rapidly stops the bleeding. What explicit surface chemistry phenomenon is fundamentally responsible for this critical styptic action?
💡 Solution & Explanation
Human blood is fundamentally a colloidal dispersion of strictly negatively charged albuminoid substances. Highly charged cations like $Fe^{3+}$ (from $FeCl_3$) and $Al^{3+}$ (from alum) efficiently and rapidly neutralize this negative surface charge according to the Hardy-Schulze rule, causing immediate massive coagulation (clotting) that physically seals the wound.