Which of the following thermodynamic changes accurately describe the adsorption of nitrogen gas on f β Surface Chemistry Chemistry Question
Question
Which of the following thermodynamic changes accurately describe the adsorption of nitrogen gas on finely divided iron?
Answer: A,C,D
π‘ Solution & Explanation
Adsorption is universally an exothermic process ($\Delta H < 0$), making A correct. The entropy actually decreases because nitrogen gas loses its freedom of movement upon hitting the surface, so B is incorrect. The driving force is the neutralization of residual surface forces (decrease in surface energy), making C correct. At equilibrium, $\Delta G = 0$, leading to $\Delta H = T\Delta S$, making D correct.
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