Surface ChemistryhardMCQ MULTIPLE

Which of the following thermodynamic changes accurately describe the adsorption of nitrogen gas on fSurface Chemistry Chemistry Question

Question

Which of the following thermodynamic changes accurately describe the adsorption of nitrogen gas on finely divided iron?

Answer: A,C,D

💡 Solution & Explanation

Adsorption is universally an exothermic process ($\Delta H < 0$), making A correct. The entropy actually decreases because nitrogen gas loses its freedom of movement upon hitting the surface, so B is incorrect. The driving force is the neutralization of residual surface forces (decrease in surface energy), making C correct. At equilibrium, $\Delta G = 0$, leading to $\Delta H = T\Delta S$, making D correct.

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