Solutions and Colligative PropertieshardMCQ MULTIPLE

Which of the following statements regarding the fundamental relationship between the degree of dissoSolutions and Colligative Properties Chemistry Question

Question

Which of the following statements regarding the fundamental relationship between the degree of dissociation/association ($\alpha$) and the van't Hoff factor ($i$) are thermodynamically and mathematically correct for a solute dissolving in a solvent?

Answer: A,B,D

💡 Solution & Explanation

For complete dissociation ($\alpha = 1$), $i = 1 + 1(n-1) = n$ (A). For association, $i = 1 + \alpha(1/n - 1)$; since $1/n < 1$ for any $n \ge 2$, $i$ is strictly $< 1$ (B). If $M_{obs} = 2 M_{theo}$, $i = 0.5$, which matches $n=2, \alpha=1$ (100% dimerization) (D). For a non-electrolyte, $i=1$, not $0$, as particles remain intact (C is incorrect).

💬
Still have doubts about this question?
Send it to our AI chemistry tutor on WhatsApp — gets answered in minutes
Ask on WhatsApp →

Practice 22,000+ questions like this

AI-adaptive practice, video lectures, and full JEE Advanced Chemistry content — all in one place.

JEE Advanced · JEE Mains · NEET · IChO · AP Chemistry