Solutions and Colligative PropertieshardMCQ MULTIPLE

Which of the following analytical chemical statements regarding the Van't Hoff factor () are mathemaSolutions and Colligative Properties Chemistry Question

Question

Which of the following analytical chemical statements regarding the Van't Hoff factor ($i$) are mathematically and thermodynamically correct?

Answer: A,C,D

💡 Solution & Explanation

For complete trimerization, $\alpha=1$, so $i = 1 + 1(1/3 - 1) = 1/3 = 0.333$ (A). For a binary weak electrolyte ($n=2$), $i = 1 + \alpha(2-1) = 1 + \alpha$. If $\alpha=0.5$, $i=1.5$ (C). Statement D correctly provides the classic textbook definition of $i$. Statement B is false; non-electrolytes that neither dissociate nor associate have $i = 1$, because they remain as intact single molecules in solution, not zero.

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