Which of the following crystalline compounds are highly prone to exhibiting the Schottky defect, pri — Solid State Chemistry Question
Question
Which of the following crystalline compounds are highly prone to exhibiting the Schottky defect, primarily because they possess high coordination numbers and have cations and anions of roughly similar sizes?
Answer: A,B,C
💡 Solution & Explanation
The Schottky defect is favored in ionic compounds where the cation and anion are of almost similar sizes and the coordination number is high. Classic examples include $NaCl$, $KCl$, $CsCl$, and $AgBr$. $ZnS$ exhibits Frenkel defects because $Zn^{2+}$ is much smaller than $S^{2-}$ and the coordination number is low (4:4).
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