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Which of the following ionic compounds share the Rock Salt () crystal structure (where anions form aSolid State Chemistry Question

Question

Which of the following ionic compounds share the Rock Salt ($NaCl$) crystal structure (where anions form a ccp lattice and cations occupy all octahedral voids)?

Answer: A,B,C

💡 Solution & Explanation

$KCl$, $AgCl$, $AgBr$, and oxides/sulphides of alkaline earth metals like $MgO$, $CaO$, $SrO$ all typically exhibit the Rock Salt ($NaCl$) structure (C.N. 6:6). $CsCl$ has a different structure where $Cl^-$ is simple cubic and $Cs^+$ is in the cubic void (C.N. 8:8).

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