s Block ElementshardNUMERICAL

Consider the sulphates of the alkaline earth metals: , , , , . How many of these compounds are classs Block Elements Chemistry Question

Question

Consider the sulphates of the alkaline earth metals: $BeSO_4$, $MgSO_4$, $CaSO_4$, $SrSO_4$, $BaSO_4$. How many of these compounds are classified as "readily soluble" in water at room temperature (where hydration energy largely overcomes lattice energy)?

Answer: 2

💡 Solution & Explanation

The solubility of alkaline earth metal sulphates decreases rapidly down the group. Because of the extremely high hydration enthalpies of the small $Be^{2+}$ and $Mg^{2+}$ ions, only $BeSO_4$ and $MgSO_4$ are considered readily soluble in water. $CaSO_4$ is sparingly soluble, and $SrSO_4$ and $BaSO_4$ are virtually insoluble.

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