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How many of the following carbonates do NOT decompose on prolonged strong heating (up to ), but raths Block Elements Chemistry Question

Question

How many of the following carbonates do NOT decompose on prolonged strong heating (up to $1000^\circ\text{C}$), but rather melt without chemical breakdown? ($Li_2CO_3$, $Na_2CO_3$, $K_2CO_3$, $Rb_2CO_3$, $Cs_2CO_3$, $MgCO_3$, $CaCO_3$)

Answer: 4

💡 Solution & Explanation

All alkaline earth metal carbonates (like $MgCO_3$, $CaCO_3$) decompose on heating. Lithium carbonate ($Li_2CO_3$) also decomposes. The carbonates of the heavier alkali metals ($Na, K, Rb, Cs$) possess very high thermal stability due to low polarizing power of their cations, so they melt without decomposing. Total = 4.

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