Reaction MechanismmediumMCQ SINGLE

Arrange the following carbonyl compounds in decreasing order of their reactivity towards nucleophiliReaction Mechanism Chemistry Question

Question

Arrange the following carbonyl compounds in decreasing order of their reactivity towards nucleophilic addition reactions: Formaldehyde (I), Acetaldehyde (II), Acetone (III), Diethyl ketone (IV).

Answer: A

💡 Solution & Explanation

The rate of nucleophilic addition to carbonyl compounds decreases as steric hindrance at the carbonyl carbon increases. Alkyl groups also exert a $+I$ (electron-donating) effect, which reduces the electrophilicity (positive charge) of the carbonyl carbon. Therefore, aldehydes are generally more reactive than ketones, and smaller groups lead to higher reactivity. The correct order is Formaldehyde > Acetaldehyde > Acetone > Diethyl ketone.

💬
Still have doubts about this question?
Send it to our AI chemistry tutor on WhatsApp — gets answered in minutes
Ask on WhatsApp →

Practice 22,000+ questions like this

AI-adaptive practice, video lectures, and full JEE Advanced Chemistry content — all in one place.

JEE Advanced · JEE Mains · NEET · IChO · AP Chemistry