Considering the addition of carbenes to alkenes, which of the following statements correctly disting β Reaction Mechanism Chemistry Question
Question
Considering the addition of carbenes to alkenes, which of the following statements correctly distinguishes between singlet and triplet carbenes?
Answer: C
π‘ Solution & Explanation
A singlet carbene has paired electrons in a single orbital, allowing for a concerted, stereospecific addition across the $\pi$ -bond of an alkene, preserving the original stereochemistry (cis/trans). A triplet carbene behaves as a diradical, adding in two distinct steps. The intermediate diradical can undergo bond rotation before ring closure, leading to a loss of original stereochemistry (non-stereospecific).
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