Qualitative and Quantitative AnalysishardNUMERICAL

In the standard qualitative analysis framework, gas is passed through a dilute solution to precipitaQualitative and Quantitative Analysis Chemistry Question

Question

In the standard qualitative analysis framework, $H_2S$ gas is passed through a dilute $HCl$ solution to precipitate Group II cations as sulphides. From the following list of cations, how many exclusively belong to Group II? List: $Pb^{2+}, Cu^{2+}, As^{3+}, Sb^{3+}, Bi^{3+}, Sn^{2+}, Cd^{2+}, Ni^{2+}, Zn^{2+}$

Answer: 7

💡 Solution & Explanation

Group II cations are those with sufficiently low $K_{sp}$ for their sulphides to precipitate in an acidic medium. The cations $Pb^{2+}$ (also in Group I but partially passes to II), $Cu^{2+}, As^{3+}, Sb^{3+}, Bi^{3+}, Sn^{2+},$ and $Cd^{2+}$ belong to Group II (Total = 7). The cations $Ni^{2+}$ and $Zn^{2+}$ belong to Group IV and require a basic medium ($NH_4OH$) to precipitate as sulphides.

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