Certain basic radicals precipitate as hydroxides which are amphoteric in nature. Which of the follow — Qualitative and Quantitative Analysis Chemistry Question
Question
Certain basic radicals precipitate as hydroxides which are amphoteric in nature. Which of the following metal hydroxides will readily dissolve in an excess of aqueous $NaOH$ to form soluble complex ions?
💡 Solution & Explanation
Aluminum, Zinc, and Chromium hydroxides are amphoteric. When excess strong base (like NaOH) is added, they dissolve to form their respective soluble hydroxo-complexes: tetrahydroxoaluminate ($[Al(OH)_4]^-$), tetrahydroxozincate ($[Zn(OH)_4]^{2-}$), and tetrahydroxochromate ($[Cr(OH)_4]^-$). Iron(III) hydroxide ($Fe(OH)_3$) is strictly basic and remains as a reddish-brown precipitate in excess NaOH.