Practical Organic Chemistry and PurificationhardNUMERICAL

In Dumas' method, of an organic compound yields of nitrogen gas collected at standard temperature anPractical Organic Chemistry and Purification Chemistry Question

Question

In Dumas' method, $0.14\ \text{g}$ of an organic compound yields $22.4\ \text{mL}$ of nitrogen gas collected at standard temperature and pressure (STP). Calculate the percentage of nitrogen in the compound. (Assume molar volume of gas at STP = $22400\ \text{mL}$)

Answer: 20

💡 Solution & Explanation

In Dumas' method, the mass of nitrogen is derived from its volume at STP. 22400 mL of $N_2$ weighs 28 g. Therefore, 22.4 mL of $N_2$ weighs $\frac{28}{22400} \times 22.4 = 0.028\ \text{g}$. The percentage of Nitrogen = $\frac{0.028}{0.14} \times 100 = 20\%$.

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