When both nitrogen and sulphur are present in an organic compound, Lassaigne's test yields a blood-r — Practical Organic Chemistry and Purification Chemistry Question
Question
When both nitrogen and sulphur are present in an organic compound, Lassaigne's test yields a blood-red coloration instead of Prussian blue upon the addition of $Fe^{3+}$ ions. This is due to the formation of:
Answer: A
💡 Solution & Explanation
When both N and S are present, sodium fusion forms sodium thiocyanate ($NaSCN$). The addition of $Fe^{3+}$ ions reacts with $SCN^-$ to form the blood-red complex iron(III) thiocyanate, $Fe(SCN)_3$ or $[Fe(SCN)]^{2+}$.
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