Practical Organic Chemistry and PurificationhardMCQ SINGLE

Which of the following statements is strictly true regarding the purification of -nitrophenol from -Practical Organic Chemistry and Purification Chemistry Question

Question

Which of the following statements is strictly true regarding the purification of $o$ -nitrophenol from $p$ -nitrophenol via steam distillation?

Answer: A

💡 Solution & Explanation

$o$ -nitrophenol exhibits intramolecular hydrogen bonding, preventing association between molecules, thereby making it steam volatile. $p$ -nitrophenol forms intermolecular hydrogen bonds, leading to molecular association and lower volatility, meaning it is not steam volatile.

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