PolymershardMCQ SINGLE

During the vulcanization of natural rubber with sulphur, what specific sites on the polyisoprene chaPolymers Chemistry Question

Question

During the vulcanization of natural rubber with sulphur, what specific sites on the polyisoprene chains are primarily attacked to form the intermolecular $-S-S-$ cross-links?

Answer: C

💡 Solution & Explanation

Vulcanization involves heating rubber with sulphur. The sulphur forms cross-links (bridges) between separate polymer chains specifically at the highly reactive allylic carbon positions (next to the double bond) or directly across the double bonds themselves.

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