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Bakelite is manufactured by extensively heating the linear prepolymer Novolac with an excess of formPolymers Chemistry Question

Question

Bakelite is manufactured by extensively heating the linear prepolymer Novolac with an excess of formaldehyde. What is the primary macroscopic and structural change that converts Novolac into Bakelite?

Answer: C

💡 Solution & Explanation

Heating Novolac with formaldehyde causes further electrophilic aromatic substitution, creating extensive methylene ($-CH_2-$) cross-links between separate linear chains at available ortho and para sites. This yields Bakelite, a rigid, infusible, thermosetting 3D network polymer.

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