PolymershardMCQ SINGLE

Unlike free-radical polymerisation, purely anionic polymerisation systems (conducted in highly purifPolymers Chemistry Question

Question

Unlike free-radical polymerisation, purely anionic polymerisation systems (conducted in highly purified, inert solvents) exhibit a unique kinetic behavior regarding their termination step. Which of the following describes this behavior?

Answer: B

💡 Solution & Explanation

In purely anionic polymerizations without impurities (like water, oxygen, or acids), the growing chain ends are carbanions which repel each other, preventing termination by combination. Unless a quenching agent is added, the active centers remain indefinitely, forming what are known as "living polymers."

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