Periodic Table and PeriodicityhardNUMERICAL

What is the calculated Mulliken scale electronegativity of an unknown element if its first ionizatioPeriodic Table and Periodicity Chemistry Question

Question

What is the calculated Mulliken scale electronegativity of an unknown element if its first ionization potential is experimentally determined to be $14.5 \text{ eV/atom}$ and its electron affinity is $3.5 \text{ eV/atom}$?

Answer: 9

💡 Solution & Explanation

The Mulliken scale defines electronegativity as the simple arithmetic average of the Ionization Potential (IP) and Electron Affinity (EA) when both are expressed in $\text{eV/atom}$. $EN_M = \frac{IP + EA}{2}$. Substituting the values: $EN_M = \frac{14.5 + 3.5}{2} = \frac{18.0}{2} = 9$.

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