Periodic Table and PeriodicityhardNUMERICAL

Among the representative elements belonging to the 3rd period of the modern periodic table (from to Periodic Table and Periodicity Chemistry Question

Question

Among the representative elements belonging to the 3rd period of the modern periodic table (from $Na$ to $Ar$), exactly how many elements exhibit a strictly higher first ionization enthalpy ($IE_1$) than Aluminium ($Al$)?

Answer: 6

💡 Solution & Explanation

The expected $IE_1$ trend across the 3rd period is $Na < Mg < Al < Si < P < S < Cl < Ar$. However, due to the stability of $Mg$'s filled $3s^2$ subshell compared to $Al$'s $3p^1$, $Mg > Al$. The actual trend is $Na < Al < Mg < Si < S < P < Cl < Ar$. The elements with higher $IE_1$ than $Al$ are $Mg, Si, S, P, Cl,$ and $Ar$. The total number is 6.

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