The atomic radii decrease from to , remain almost constant from to , and slightly increase for in th — Periodic Table and Periodicity Chemistry Question
Question
The atomic radii decrease from $Sc$ to $V$, remain almost constant from $Cr$ to $Cu$, and slightly increase for $Zn$ in the $3d$ transition series. The constancy in radii from $Cr$ to $Cu$ is best explained by:
Answer: B
💡 Solution & Explanation
In the middle of the $3d$ series, electrons are progressively added to the inner $3d$ subshell. The added screening effect of these $3d$ electrons strongly shields the outermost $4s$ electrons, effectively counterbalancing the increased nuclear pull, resulting in almost constant radii.
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