p Block ElementshardMCQ MULTIPLE

Which of the following statements are correct regarding the structure and chemistry of Borax ()?p Block Elements Chemistry Question

Question

Which of the following statements are correct regarding the structure and chemistry of Borax ($Na_2[B_4O_5(OH)_4] \cdot 8H_2O$)?

Answer: A,C

💡 Solution & Explanation

Borax contains the $[B_4O_5(OH)_4]^{2-}$ ion, where two B atoms are $sp^2$ hybridized and two are $sp^3$ hybridized. This ion features 5 B-O-B bridging oxygen atoms (10 B-O bonds) and 4 terminal -OH groups (4 B-O bonds), totaling 14 B-O bonds. Its aqueous solution is alkaline (buffer of $NaOH$ and $H_3BO_3$), and heating it yields glassy $B_2O_3$ and $NaBO_2$, not $H_3BO_3$.

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