Metallurgy and Isolation of ElementshardNUMERICAL

During the purification of Zirconium via the Van Arkel method, the impure Zirconium solid reacts witMetallurgy and Isolation of Elements Chemistry Question

Question

During the purification of Zirconium via the Van Arkel method, the impure Zirconium solid reacts with Iodine gas to form a highly volatile, covalent intermediate. Let $x$ be the formal oxidation state of Zirconium in this volatile compound. Determine the exact value of $x$.

Answer: 4

💡 Solution & Explanation

The volatile intermediate formed in the Van Arkel purification of Zirconium is Zirconium tetraiodide, with the chemical formula $ZrI_4$. The oxidation state of Zr in $ZrI_4$ is $+4$. Therefore, $x = 4$.

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