During the continuous operation of the Hall-Heroult electrolytic cell for aluminium extraction, the — Metallurgy and Isolation of Elements Chemistry Question
Question
During the continuous operation of the Hall-Heroult electrolytic cell for aluminium extraction, the carbon (graphite) anodes must be periodically replaced. Which specific reaction necessitates this replacement?
Answer: C
💡 Solution & Explanation
During electrolysis, oxygen ions migrate to the anode. The liberated oxygen reacts aggressively with the carbon of the anode at high temperatures to form $CO$ and $CO_2$ gases, continuously eroding and consuming the graphite rod, which must therefore be replaced.
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