Based on the principles depicted in the Ellingham diagram ( vs ), which of the following deductions — Metallurgy and Isolation of Elements Chemistry Question
Question
Based on the principles depicted in the Ellingham diagram ($\Delta G^\circ$ vs $T$), which of the following deductions are chemically sound?
Answer: A,B,C
💡 Solution & Explanation
At intersection, $\Delta G^\circ_{coupled} = 0$. Metals with lower curves have higher oxygen affinity and can reduce oxides of metals on upper curves. Most metal oxide plots have a positive slope, meaning $\Delta G^\circ$ becomes less negative with increasing temperature. The plot for $C \rightarrow CO_2$ has $\Delta S \approx 0$ (1 mole gas to 1 mole gas), yielding a horizontal line, not a steep positive slope.
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