IUPAC and NomenclaturehardMCQ MULTIPLE

Consider the numbering rules for functionalized bicyclic and spirocyclic compounds. Which of the folIUPAC and Nomenclature Chemistry Question

Question

Consider the numbering rules for functionalized bicyclic and spirocyclic compounds. Which of the following statements are correct?

Answer: A,C

💡 Solution & Explanation

Numbering in bicyclo compounds strictly follows the decreasing bridge length rule regardless of substituent or functional group placement (C is correct, B is false). Spiro numbering starts in the small ring and passes through the spiro carbon (A is correct), meaning the spiro carbon is never number 1 (D is false).

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