Isomerism and StereochemistryhardMCQ MULTIPLE

When applying the general formula to calculate the total number of stereoisomers for an unsymmetricaIsomerism and Stereochemistry Chemistry Question

Question

When applying the general formula $2^n$ to calculate the total number of stereoisomers for an unsymmetrical organic compound, the value '$n$' represents the aggregate sum of all stereogenic units. Which of the following specific chemical entities properly qualify as valid stereogenic units to be counted in '$n$'?

Answer: A,B,C

💡 Solution & Explanation

Stereogenic units include any structural site where interchanging two attached groups creates a new, physically distinct stereoisomer. This explicitly includes classical chiral centers (B), stereogenic double bonds exhibiting restricted rotation (A), and cyclic rings restricting rotation (C). Alkynes (D) are strictly linear ($180^\circ$) and entirely lack the geometry required to display geometrical or optical isomerism.

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