In a standard even-cumulene system possessing exactly two adjacent pi bonds (an allene framework), w β Isomerism and Stereochemistry Chemistry Question
Question
In a standard even-cumulene system possessing exactly two adjacent pi bonds (an allene framework), what is the calculated dihedral angle (in degrees) physically established between the two planes containing the respective terminal valencies?
π‘ Solution & Explanation
In an allene (even cumulene) system, the central $sp$ hybridized carbon forms two mutually perpendicular pi bonds using its two unhybridized p-orbitals. Consequently, the groups attached to the terminal $sp^2$ hybridized carbons are geometrically locked in mutually perpendicular planes. The dihedral angle spanning between these orthogonal terminal planes is $90^\circ$.