In organic chemistry, which of the following specific molecular frameworks fundamentally possess a R — Isomerism and Stereochemistry Chemistry Question
Question
In organic chemistry, which of the following specific molecular frameworks fundamentally possess a Restricted Rotatory System (RRS) capable of generating geometrical isomerism?
Answer: A,B,D
💡 Solution & Explanation
Alkenes and imines possess pi ($\pi$) bonds that completely restrict rotation along the inter-nuclear axis. Cycloalkanes possess a rigid ring framework that similarly restricts free rotation of the single bonds forming the ring. Alkynes are inherently linear ($180^\circ$ bond angle); therefore, the spatial distances between any attached terminal groups cannot vary, rendering GI impossible.
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