Ionic EquilibriumhardNUMERICAL

When exactly of solid is carefully added to exactly of a generic acidic buffer solution, its pH demoIonic Equilibrium Chemistry Question

Question

When exactly $0.02 \text{ moles}$ of solid $NaOH$ is carefully added to exactly $1.0 \text{ L}$ of a generic acidic buffer solution, its pH demonstrably shifts from $5.75$ up to $5.80$. What is the exact mathematical buffer capacity ($\beta$) of this specific solution?

Answer: 0.4

💡 Solution & Explanation

Buffer capacity ($\beta$) is mathematically defined as the ratio of the number of moles of strong acid or strong base added per liter of buffer to the absolute change in its pH. The formula is $\beta = \frac{\Delta n / V}{\Delta pH}$. Here, $0.02 \text{ moles}$ of $NaOH$ are added to $1 \text{ L}$ ($V=1$), causing a pH change $\Delta pH = 5.80 - 5.75 = 0.05$. Therefore, $\beta = \frac{0.02}{0.05} = \frac{2}{5} = 0.4$.

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