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The cyclic polymerization of ethyne into benzene requires passing the alkyne gas through a red-hot iHydrocarbons Chemistry Question

Question

The cyclic polymerization of ethyne into benzene requires passing the alkyne gas through a red-hot iron tube. What is the optimal temperature required to achieve this trimerization?

Answer: B

💡 Solution & Explanation

Cyclic polymerization of terminal alkynes is a high-temperature process. Passing ethyne gas through a red-hot iron tube at exactly 873 K provides the necessary activation energy for the three $\pi$ bonds to break and reform into the continuous $\sigma$ and delocalized $\pi$ framework of the benzene ring.

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