HydrocarbonshardMCQ SINGLE

The electrophilic addition of liquid bromine () to *trans*-2-butene is a stereospecific reaction. WhHydrocarbons Chemistry Question

Question

The electrophilic addition of liquid bromine ($Br_2/CCl_4$) to *trans*-2-butene is a stereospecific reaction. What is the stereochemical nature of the final major product?

Answer: B

💡 Solution & Explanation

The halogenation of alkenes with $Br_2$ proceeds via a cyclic bromonium ion intermediate and involves strict *anti*-addition. The *anti*-addition of halogens to a *trans* symmetrically substituted alkene yields a *meso* compound (due to an internal plane of symmetry). Conversely, *anti*-addition to a *cis* alkene yields a racemic mixture. Thus, *meso*-2,3-dibromobutane is formed.

💬
Still have doubts about this question?
Send it to our AI chemistry tutor on WhatsApp — gets answered in minutes
Ask on WhatsApp →

Practice 22,000+ questions like this

AI-adaptive practice, video lectures, and full JEE Advanced Chemistry content — all in one place.

JEE Advanced · JEE Mains · NEET · IChO · AP Chemistry