When propyne gas is passed through a red-hot iron tube at 873 K, it undergoes cyclic polymerization. β Hydrocarbons Chemistry Question
Question
When propyne gas is passed through a red-hot iron tube at 873 K, it undergoes cyclic polymerization. What is the major aromatic product formed?
Answer: C
π‘ Solution & Explanation
Terminal alkynes undergo cyclic trimerization in a red-hot iron tube at 873 K. Three molecules of propyne ($CH_3-C\equiv CH$) orient themselves and polymerize to form an aromatic ring with three methyl groups symmetrically distributed. The product is 1,3,5-trimethylbenzene, commonly known as mesitylene.
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