HydrocarbonshardNUMERICAL

For straight-chain alkenes, the addition of each successive group to the homologous series typicallyHydrocarbons Chemistry Question

Question

For straight-chain alkenes, the addition of each successive $-CH_2-$ group to the homologous series typically increases the boiling point by a certain range. If the lower bound of this expected boiling point increase per $-CH_2-$ group is $X$ Kelvin, what is the exact value of $X$?

Answer: 20

💡 Solution & Explanation

As the molecular mass and surface area increase with each added $-CH_2-$ group, the van der Waals dispersion forces become stronger. This regular increase raises the boiling point of the homologous series by $20$ to $30$ Kelvin per $-CH_2-$ unit. Thus, the lower bound is 20 K.

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