HydrocarbonshardMCQ SINGLE

During the Wurtz reaction, side products can be formed via the disproportionation of alkyl free radiHydrocarbons Chemistry Question

Question

During the Wurtz reaction, side products can be formed via the disproportionation of alkyl free radicals. If ethyl free radicals disproportionate instead of dimerizing, what are the products?

Answer: B

💡 Solution & Explanation

In the free radical mechanism of the Wurtz reaction, ethyl radicals ($CH_3-\dot{C}H_2$) primarily dimerize to form butane. However, they can also undergo disproportionation, where one radical abstracts a hydrogen from another. This transfer creates an alkane (ethane, $CH_3-CH_3$) and an alkene (ethene, $CH_2=CH_2$) as side products.

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