GOC and Organic Chemistry BasicshardMCQ SINGLE

Which of the following halo-substituted acetic acids possesses the highest acidic strength (lowest )GOC and Organic Chemistry Basics Chemistry Question

Question

Which of the following halo-substituted acetic acids possesses the highest acidic strength (lowest $pKa$) based strictly on inductive effects?

Answer: C

💡 Solution & Explanation

Acidic strength depends directly on the stabilization of the conjugate base (carboxylate anion). Halogens stabilize the anion via the electron-withdrawing negative inductive ($-I$) effect. Since fluorine is the most electronegative element among the halogens, it exerts the strongest $-I$ pull, dispersing the negative charge most effectively and making fluoroacetic acid the strongest acid.

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