Based on hyperconjugation, which of the following isomeric dienes is expected to have the lowest ove β GOC and Organic Chemistry Basics Chemistry Question
Question
Based on hyperconjugation, which of the following isomeric dienes is expected to have the lowest overall heat of hydrogenation?
Answer: C
π‘ Solution & Explanation
The lowest heat of hydrogenation corresponds to the most stable diene. Conjugated dienes (1,3-pentadiene and isoprene) are more stable than isolated (1,4) or cumulated (1,2) dienes. Isoprene is more stable than 1,3-pentadiene because it possesses more $\alpha$ -hydrogens attached to the conjugated system, maximizing hyperconjugative stabilization.
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