Consider the following electrochemical cells under standard conditions (all aqueous concentrations , — Electrochemistry Chemistry Question
Question
Consider the following electrochemical cells under standard conditions (all aqueous concentrations $1\text{ M}$, gases at $1\text{ atm}$, $T = 298\text{ K}$). Which of these constructed cells will have a standard cell potential ($E^\circ_{cell}$) exactly equal to zero?
💡 Solution & Explanation
Cells B and C are concentration cells constructed with identical electrodes in both the anode and cathode compartments. Because the standard reduction potential of the cathode is identically equal to the standard reduction potential of the anode, the standard cell potential $E^\circ_{cell} = E^\circ_{cathode} - E^\circ_{anode} = 0$. Since concentrations are standard ($1\text{ M}$), $E_{cell}$ is also 0.