Coordination CompoundshardMCQ MULTIPLE

Sidgwick's EAN rule serves as an early model for predicting complex stability. Which of the followinCoordination Compounds Chemistry Question

Question

Sidgwick's EAN rule serves as an early model for predicting complex stability. Which of the following observations concerning its applications and limitations is/are historically and conceptually accurate?

Answer: A,B,C

💡 Solution & Explanation

(A) True: The rule works best for carbonyls and low oxidation states, failing frequently elsewhere. (B) True: A metal-metal bond is shared, adding 1 electron to the count of each metal involved. (C) True: Fe(26) + 10 = 36. Mn(25) + 10 = 35. $Mn(CO)_5$ is unstable and typically dimerizes to $Mn_2(CO)_{10}$ to reach EAN=36. (D) False: Complexes with an EAN less than the noble gas configuration lack electrons, so they act as oxidizing agents (they undergo reduction by gaining electrons), not auto-reducing agents.

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